Journal article
Frustrated magnetism in Cu(II) based metal–organic framework


Authors/Editors

Research Areas
Currently no objects available

Publication Details
Author list: Nath A., Das S., Mukharjee P., Nath R., Kuznetsov D., Mandal S.
Publisher: Elsevier
Publication year: 2019
Volume number: 486
Start page: 158
End page: 161
Number of pages: 4
ISSN: 0020-1693

Abstract

A Cu(II) based metal–organic framework (MOF), [Cu2(TPT)2(BTC)Cl]·(solvent)x, (TPT = 2,4,6-tris(4-pyridyl)-1,3,5-triazine, BTC = benzene-1,3,5-tricarboxylic acid) has been solvothermally synthesized and characterized using single crystal X-ray diffraction, powder X-ray diffraction, thermogravimetric analysis and magnetic measurements. This compound adopts three-dimensional connectivity where Cu2+dimers are linked with BTC ligand to form the layered architecture. This layered motif is pillared by TPT linker to form the three-dimensional structure. Magnetic studies show that the compound undergoes a magnetic long-range ordering at TN ≈ 5 K. A large value of Curie–Weiss temperature compared to TN suggests strongly frustrated nature of the magnetic compound.


Keywords
Currently no objects available

Documents
Currently no objects available

Last updated on 2018-09-11 at 00:00